Search Results (65)

Dunaliella salina has been recognized as an excellent biomass source of carotenoid, which can be used as a natural orange coloring agent for food products. The most eco-friendly approach for extracting carotenoid is through supercritical carbon dioxide extraction, as it yields highly concentrated extracts while preventing pigment thermal degradation. However, there are limitations when a lipophilic extract is considered a food ingredient, in particular very difficult handling and low solubility in water-based products. The aim of this study was to develop a hydrosoluble form of a natural carotenoid-rich extract recovered from algae biomass within a biorefinery concept to be incorporated in aqueous-based food products. A two-step process was developed, starting with the emulsification of the supercritical extract into a mixture of maltodextrin and gum arabic, using soy lecithin as an emulsifier. The emulsification was followed by a spray-drying step. The impact of process variables on the encapsulation yield, efficiency, emulsion properties, and particle characteristics was studied. The resulting particles exhibited an intense orange color and good water dispersibility, facilitating uniform yellow coloring when incorporated into an aqueous-based product. Overall, spray-drying emulsions containing carotenoids derived from Dunaliella salina prove to be a promising strategy for the global market demand for natural colorants. Full article

A library of seven novel 1,3-benzothiazole-substituted BODIPY derivatives with tunable optical properties was synthesized. The new fluorescent dyes exhibited bathochromically shifted absorptions (up to 670 nm) and emissions centered in the red and near-infrared spectral region (up to 677 nm) in comparison to the parent compound 8-phenyl BODIPY (λ_abs: 499 nm, λ_emi: 508 nm). (TD)DFT calculations were performed to rationalize the spectroscopic properties of the new dyes. The cellular biodistribution of the new BODIPY dyes, their fluorescence stability and toxicity were investigated in both living and fixed fibroblasts using time-lapse fluorescent imaging and confocal microscopy. Six of the seven new dyes were photostable and non-toxic in vitro at 10 μM concentration. In addition, they efficiently stained the cell membrane, showing diffuse and dotty localization within the cell at low concentrations (1.0 and 0.1 μM). Specifically, dye TC498 was localized in vesicular structures in both live and fixed cells and could be used as a suitable marker in co-staining studies with other commonly used fluorescent probes. Full article

Remediation of organic dyes in natural waters is a significant environmental need under active study. This review analyzes bimetallic catalytic degradation systems that are based on the Fenton chemistry concept and that generate reactive oxygen species (ROS) as the agent of dye breakdown. Recently developed advanced oxidation processes (AOPs) take advantage of bimetallic heterogeneous catalysts to facilitate rapid rates and full degradation. Catalysts based on two metals including iron, copper, molybdenum, cobalt and magnesium are discussed mechanistically as examples of effective radical ROS producers. The reactive oxygen species hydroxyl radical, superoxide radical, sulfate radical and singlet oxygen are discussed. System conditions for the best degradation are compared, with implementation techniques mentioned. The outlook for further studies of dye degradation is presented. Full article

Y(Mn_0.95M_0.05)₂O₅ (M = Al, Fe, Ga, Ti, and Zr) samples were synthesized via a sol–gel method using citric acid to find a new near-infrared (NIR) reflective black pigment. Among these samples, the optical reflectance of Y(Mn_0.95Fe_0.05)₂O₅ and Y(Mn_0.95Ga_0.05)₂O₅ in the near-infrared region was found to be larger than that of YMn₂O₅. Then, the concentration of the dopant (Fe or Ga) was changed between 0 and 15%, and the resulting UV–Vis–NIR reflectance spectra were measured. As a result, the optical reflectance of the Fe-doped samples decreased in the near-infrared region, while that of the Ga-doped samples increased. Accordingly, Y(Mn_1−xGa_x)₂O₅ (0 ≤ x ≤ 0.20) samples were synthesized, and the crystal structure, particle size, optical properties, and color of the samples were characterized. The single-phase samples were obtained in the composition range of 0 ≤ x ≤ 0.15, and the lattice volume decreased with increasing Ga³⁺ concentration. Optical absorption below 850 nm was attributed to the charge transfer transition between O_2p and Mn_3d orbitals, and the absorption wavelength of Y(Mn_1−xGa_x)₂O₅ shifted to the shorter wavelength side as the Ga³⁺ content increased, because of the decrease in the Mn³⁺ concentration. Although the sample color became slightly reddish black by the Ga³⁺ doping, the solar reflectance in the near-infrared region reached 47.6% at the composition of Y(Mn_0.85Ga_0.15)₂O₅. Furthermore, this NIR reflectance value was higher than those of the commercially available products (R < 45%). Full article

Due to the high stability of azo-type dyes, conventional treatment processes such as adsorption, flocculation, and activated sludge are not efficient for decolorizing wastewater effluents. An alternative to traditional wastewater treatment is photocatalysis, which has gained significant interest because research has shown it to be a viable and cost-effective process that uses sunlight as an inexhaustible energy source. In heterogeneous photocatalysis, a photocatalyst is required, such as TiO₂, ZnO, composite materials, and, more recently, metal–organic frameworks (MOFs). MOFs, also known as “coordination polymers”, exhibit photocatalytic properties and have been proven to be promising materials in the photocatalytic degradation of dyes. This study presents recent advances in using MOFs as photocatalysts to degrade recalcitrant contaminants like azo-type dyes. Recent advancements in developing photocatalysts based on MOFs are focused on two strategies. Firstly, the development of new MOFs composed of complex ligands or a mixed ligand system, and secondly, the synthesis of composite materials based on MOFs and metal oxides, metals, sulfides, nitrides, etc. Both strategies have significantly contributed to the search for new semiconductors to degrade some recalcitrate contaminants in wastewater. Full article

The design and development of sensitizing dyes possessing wide-wavelength photon harvesting encompassing visible to near-infrared (NIR) wavelength regions are unavoidable for increasing the overall efficiency of dye-sensitized solar cells (DSSCs). In this study, three far-red-sensitive squaraine sensitizers were designed computationally, synthesized, and characterized, aiming towards their suitability as a potential sensitizer for DSSCs. It has been found that the incorporation of an electron acceptor moiety in the central squaraine core brought about a red shift in the absorption maximum (λ_max) and the emergence of a secondary absorption band in the blue region, thus broadening the photon-harvesting window. In addition, it also lowered the dye’s HOMO energy level enabling a facile regeneration of the photo-excited dye, which improved the photovoltaic performance of SQ-223, exhibiting a photoconversion efficiency (PCE) of 4.67%. Thereafter, to address the issue of wide-wavelength photon harvesting, DSSCs were fabricated by co-adsorbing two complementary dyes SQ-223 and D-131 in various molar ratios. The DSSC fabricated with D-131 and SQ-223 in 9:1 molar ratio displayed the best photovoltaic performance with a PCE of 5.81%, a significantly higher PCE when compared to corresponding individual dye-based DSSCs containing D-131 (3.94%) and SQ-223 (4.67%). Full article

Two of the most significant cases of extant 16th-century featherwork from Mexico are the so-called Moctezuma’s headdress and the Ahuizotl shield. While the feathers used in these artworks exhibit lightfast colors, their assembly comprises mainly organic materials, which makes them extremely fragile. Printed media, including books, catalogs, educational materials, and fine copies, offer an accessible means for audiences to document and disseminate visual aspects of delicate cultural artifacts without risking their integrity. Nevertheless, the singular brightness and iridescent colors of feathers are difficult to communicate to the viewer in printed reproductions when traditional pigments are used. This research explores the use of effect pigments (multilayered reflective structures) and improved halftoning techniques for additive printing, with the objective of enhancing the reproduction of featherwork by capturing its changing color and improving texture representation via a screen printing process. The reproduced images of featherwork exhibit significant perceptual resemblances to the originals, primarily owing to the shared presence of structural coloration. We applied structure-aware halftoning to better represent the textural qualities of feathers without compromising the performance of effect pigments in the screen printing method. Our prints show angle-dependent color, although their gamut is reduced. The novelty of this work lies in the refinement of techniques for printing full-color images by additive printing, which can enhance the 2D representation of the appearance of culturally significant artifacts. Full article

Herein, we evaluate the conversion efficiency of dye-sensitized solar cells (DSSCs) photosensitized using two different natural dyes extracted from Alpinia purpurata and Alstroemeria flower petals. The appreciable absorption capacity of the extracts in the visible light region was examined through absorption spectroscopy. The functional groups of the corresponding pigments were identified through Fourier transform spectroscopy (FTIR) technique thus indicating the presence of cyanidin 3-glycosides and piperine in the flowers of Alstroemeria and Alpinia purpurata. The extracted dyes were immobilized on TiO₂ on transparent conducting FTO glass, which were used as photoanode. The dye-coated TiO₂ photoanode, pt photocathode and iodide/triiodide redox electrolyte assembled into a cell module was illuminated by a light source intensity 100 mW/cm² to measure the photovoltaic conversion efficiency of DSSCs. The TiO₂ anode and Pt counter electrode surface roughness and morphological studies were evaluated using atomic force microscope (AFM) and field emission scanning electron microscopy (FESEM), respectively. Through the photoelectric characterizations, it was promising to verify that the solar conversion efficiency was calculated with the photovoltaic cell sensitized by Alstroemeria and Alpinia purpurata. This was achieved with a yield (η) of 1.74% and 0.65%, with an open-circuit voltage (V_oc) of 0.39 and 0.53 V, short-circuit current density (J_sc) of 2.04 and 0.49 mA/cm², fill factor (FF) of 0.35 and 0.40, and P_max of 0.280 and 0.100 mW/cm², respectively. The results are promising and demonstrate the importance of the search for new natural dyes to be used in organic solar cells for the development of devices that generate electricity in a sustainable way. Full article

This work provides significant insight into the molecular structure of alizarin lake pigments used by artists in the past. To characterize two red powders, lakes 1 and 2, obtained by complexation of 1,2-dihydroxy anthraquinone (alizarin) with Al³⁺_, a multi-analytical approach was designed based on solid and liquid state Nuclear Magnetic Resonance Spectroscopy (NMR), Fourier-Transform Infrared Spectroscopy (FTIR), Mass Spectrometry (MS) and Density Functional Theory (DFT) calculations. Lake 1 was synthesized according to literature and compared with lake 2, a reproduction of an artist’s pigment. FTIR showed Al³⁺ coordinated to oxygens in C1 and C9, and that in lake 2 the -OH groups in C2 are protonated, being responsible for its low solubility. ¹H-NMR proved that lake 2 is formed by two tautomers [Al(Aliz-₂-H-)₂(OH)(H₂O)] and [Al(Aliz-₁₀-H-)₂(OH)(H₂O)], the latter being the major species. SS-NMR was the only technique that got insight into the Al³⁺ coordination, octahedral for both lakes. It confirmed the existence of two species in lake 2, in a 5:1 ratio. Both are amorphous “open structures”, resulting in fewer constraints for the ligands and in a large variety of geometries. SS-NMR allowed the analysis of the red pigments without preparation, which is a unique advantage for their study in artworks. Full article

Derived from malachite green, new triaryl-carbonium-ion-functionalized gold nanoparticles have been synthesized for detecting anions. The detection process, and concomitant colour change, is based on charge compensation on the surface of nanoparticles, which triggers their aggregation, resulting in a bathochromic shift of the plasmon resonance band. The difference in electrophilicity of the malachite green triaryl ions in solution or on gold nanoparticles makes it possible to distinguish different anions related to their nucleophilic character. Full article

Blue dyes are relatively uncommon in nature, and a novel dithiophene dye (RanB) is reported in this paper. This dye is derived from an old anti-osteoporotic drug and is a metal ion complexing agent, displaying a planar molecular structure, with two sets of carboxylate, isonitrile, thiophene, and iminodiacetate groups. The blue color originates from a strong absorption peak at 648 nm, accompanied by an unusual fluorescence at 555 nm, with higher energy compared to the main absorption band. RanB forms complexes with lanthanoid ions through the iminodiacetate groups and serves as an effective sensitizer for Tb³⁺ ions, heightening their emission and improving their use as luminescent agents. Its photo-physical properties and the interaction with Tb³⁺ have been investigated using absorption spectroscopy, steady-state and time-resolved fluorescence spectroscopy, along with computational methods (ZINDO/S and DFT). The RanB toxicity in human umbilical vein endothelial cells has also been tested, showing a lack of toxicity, holding promising prospects for application as a luminescent and coloring agent in pharmaceuticals and food. Full article

Zinc hydroxide nitrate (ZHN) was used as an anionic adsorbent for the removal of methyl orange (MO) dye from aqueous solutions. ZHN was characterized via X-ray diffraction (XRD) and infrared spectroscopy (FTIR) techniques. Investigations were carried out to see how the adsorption of MO was affected by factors such as initial MO concentration, contact time and temperature. Adsorption isotherms were analyzed using the Langmuir and Freundlich equations, with the first one being the better result for the equilibrium data. Adsorption kinetics was studied through applying pseudo-first and pseudo-second-order kinetic models, and the experimental data were better fitted to the pseudo-second-order model. The activation energy was determined using the Arrhenius equation to be 105.45 kJ mol⁻¹, revealing the chemical nature of the adsorption process. The thermodynamic parameters were also determined, showing the adsorption of MO onto ZHN to be a non-spontaneous and exothermic process. The experimental results showed ZHN as a potential adsorbent with adsorption capacity for removing anionic dyes from water medium. Full article

Surface fluorination with pure F₂ gas can easily make the surface on PP (polypropylene) hydrophobic, and it causes limited dyeability, as reported in a previous paper. In this study, to produce a more hydrophilic surface, surface fluorination of PP was performed at 25 °C, total gas pressure of 13.3 kPa, and reaction time of 1 h using F₂ and O₂ mixtures with different proportions of F₂ gas. The surface roughness of the fluorinated PP samples was about 1.5 times higher than that of the untreated sample (5 nm). Fourier-transform infrared spectroscopy and X-ray photoelectron spectroscopy (XPS) results showed that the PP-derived bonds (-C-C- and -CH_x) decreased because they were converted into polar groups (-C–O, -CHF-, and -CF_x), which increased the surface electronegativity of the PP. The variation in the F₂ gas proportion in the gas mixture significantly affected the hydrophilicity and surface composition of the PP. At F₂ gas proportions of <70%, the hydrophilicity of the fluorinated PP samples was increased. Notably, the hydrophilic and negatively charged PP surface enhanced the dyeing of the polymer with basic methylene blue (MB). In contrast, at F₂ gas proportions of >90%, the PP surface became hydrophobic owing to increased numbers of hydrophobic -CF₃ bonds. Thus, enhanced PP dyeing can be controlled based on the composition of the F₂ and O₂ gas mixture. Full article

The 18th century roof tiles from the “Casa delle vigne”, located in the Aosta region (north-east Italy), were investigated as an example of a peculiar historical roof covering: ceramic tiles with a lead-based glaze finishing to waterproof them are used to create colourful patterns. A conservation project proposed the integration of the original tiles with new ones, produced according to traditional methods. Ancient and new tiles were analysed with Fiber Optics Reflectance Spectroscopy, micro-Raman, Fourier Transform Infrared Spectroscopy and X-ray Fluorescence Spectrometry, Thermogravimetry and Differential Scanning Calorimetry for understanding the composition and the production technology of this manufacture. Their resistance to freezing and thawing cycles was then tested, considering their exposure in the severe alpine climate of Aosta. The use of pure clays with low calcium contents, high firing temperature and lead-rich glazes was found in ancient tiles, able to outstand several freezing-thawing cycles without damages. Iron and copper pigments were used in old yellow and green glazes. Zinc-based pigment, low lead and calcium-rich glazes are used in the new ones, which remained mainly coherent to the ceramic body during the freeze-thaw test. Full article

In this study, a new red ceramic pigment has been developed within a perovskite structure, and microwave heat treatments have been applied. Those red ceramic pigments within the YAlO₃ system doped with chromium with the nominal composition Y_0.98Al_0.98Cr_0.04O₃ were synthesized by traditional routes and alternative methods like coprecipitation. Also, heat treatment has been studied comparing a traditional electric and microwave kiln. Different flux agents have been incorporated to improve the synthesis reaction. Prepared pigments have been characterized by X-ray diffraction (XRD) as having a predominant phase of perovskite structure, which is responsible for the red shade, and a minority garnet phase that causes more brown colorations. Studies by Ultraviolet-Visible spectroscopy gave rise to a series of absorption bands that indicate the presence of Cr(III) in the octahedral position corresponding to perovskite and Cr(IV) corresponding to garnet in both the octahedral and tetrahedral positions. The perovskite phase is favored with the use of flux mix, corroborating the UV-visible results and being more pronounced in traditional high temperature thermal treatments. The coprecipitation route has been studied to increase the reactivity of the particles given their nanometric size; however, this reactivity favors a greater appearance of undesirable garnet phases with both types of flux. Scanning Electron Microscopy (SEM) micrographs offer information obtained from the secondary electrons of predominantly cubic crystalline phases with sizes between 1 µm and 2 µm in pigments synthesized via the traditional method and sizes less than 1µm together with the glassy phase in pigments synthesized via coprecipitation. Microwave thermal treatments have been studied, obtaining pigments with a majority structure of perovskite and garnet at lower temperatures and relatively short synthesis times. The feasibility of use in porous single-fired ceramic glazes has been studied, whose chromatic coordinates have been collected using an Ultraviolet-Visible Spectrophotometer based on the CIEL*a*b* system. Full article